2011
DOI: 10.1146/annurev-fluid-122109-160756
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Surfactant Effects on Bubble Motion and Bubbly Flows

Abstract: Small amounts of surfactant can drastically change bubble behavior. For example, a bubble in aqueous surfactant solution rises much slower than one in purified water. This phenomenon is explained by the so-called Marangoni effect caused by a nonuniform concentration distribution of surfactant along the bubble surface. In other words, a tangential shear stress appears on the bubble surface due to the surface tension variation caused by the surface concentration distribution, which results in the reduction of th… Show more

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Cited by 230 publications
(139 citation statements)
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References 42 publications
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“…Moreover, according to our visualization in the x−y and x−z planes, both the bubble-wall attachment as seen for smaller bubbles (Fig. 1) and the bubble cluster as seen in a vertical channel bubbly flow [39] do not occur at any φ, even though rising bubbles are located close to the wall, especially at φ=40˚. We speculate that the former relates to the buoyancy/surface tension ratio of injected bubbles, while the latter relates mainly to their interface shape and local bubble number density.…”
Section: Bubble Concentration and Wall-parallel Mean Velocity Of Bubblessupporting
confidence: 56%
“…Moreover, according to our visualization in the x−y and x−z planes, both the bubble-wall attachment as seen for smaller bubbles (Fig. 1) and the bubble cluster as seen in a vertical channel bubbly flow [39] do not occur at any φ, even though rising bubbles are located close to the wall, especially at φ=40˚. We speculate that the former relates to the buoyancy/surface tension ratio of injected bubbles, while the latter relates mainly to their interface shape and local bubble number density.…”
Section: Bubble Concentration and Wall-parallel Mean Velocity Of Bubblessupporting
confidence: 56%
“…The approach developed in this paper may be coupled with a realistic model of surfactant transport 12,44 to assess the changes induced in the wake dynamics by the adsorption/desorption and surface transport mechanisms that drive the contamination of bubbles in many real fluids, especially water. Nevertheless the next step of this stream of research performed in our group will still consider clean bubbles.…”
Section: Discussionmentioning
confidence: 99%
“…This features suggest that a disturbance applied on the rear part of the bubble surface, especially close to its symmetry axis, should significantly modify the stability of the wake. It may also be related to the well-known sensitivity of bubble paths to the presence of minute amounts of surfactants which are swept to the rear of the bubble by the base flow and modify the boundary condition, from shear-free to no-slip, in that region 12,34 .…”
Section: B Receptivity To a Localized Feedbackmentioning
confidence: 99%
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“…気泡流には様々なスケールがあり、気泡が生成 する乱れは多くの研究者の注目を集めている。そ の乱れは、流れ場と相互作用し、単相流とは異な る複雑な流動構造を示す [1][2][3][4][5][6]。特に気泡クラスタ ーは、乱流の秩序渦構造よりも大きく、大規模な 流動構造そのものを変化させる [7,8]。 そのため気 泡クラスター形成の有無について様々な報告が 行われている [9][10][11]。 気泡のクラスター形成は、まず理論的に予測さ れた。ポテンシャル流れを仮定し、複数の気泡が 上昇する際、気泡間相互作用によって水平面に気 泡 が クラスターを 形成することが報告された [12,13]。一方で、実際の気泡流では、気泡同士の 合体によって気泡径差が生まれ、通常気泡のクラ スター構造は観察されない。さらに前述のポテン シャル流れを用いた理論でも、気泡径差を考慮す るとクラスターは形成されない [14]。しかし、実 験的研究において、界面活性剤や電解質を混入さ せることで気泡クラスターの形成が報告されて いる [15,16]。 界面活性剤や電解質の混入は、気泡表面の境界 条件を大きく変化させる。界面活性剤では気泡の 抗力の増加や合体を防ぎ、電解質ではやクリーン な気泡を保ちながら気泡合体を防ぐ [17][18][19][20] /01 02 0/%/ü ! 1 ö 3 4 5 6 7 8 9 6 % !ú ÷ ù ' ü ü ö !…”
Section: 緒 言unclassified