“…Mine drainage is likely to release toxic metals/metalloids into shallow groundwater around coal mines . Previous studies have identified coal-mine drainage by relatively high SO 4 and low Br and Ba concentrations as compared to saline fluids associated with oil and gas production. ,, Conventional oil and gas development may have contaminated shallow groundwater mainly due to surface spills (e.g., hydrocarbons, produced waters) and upward migration of saline fluids along improperly cased/cemented wells and unplugged or improperly plugged abandoned wells . Differentiating between produced waters from conventional and unconventional hydrocarbon reservoirs is challenging, although ratios of major ions and isotopic compositions of Sr, B, Li, Ba, and Ra can provide a unique fingerprint for each reservoir. ,,,,,,, However, the distinction between produced waters from conventional and unconventional reservoirs is not always possible due to geochemical overlaps. ,, To our knowledge, no pre-development baseline investigations have documented legacy groundwater contamination from previous hydrocarbon operations in shale gas development areas.…”