Some target tiles of the W7-AS divertor has been investigated with respect to their thermal behaviour at the surface during power loading with well defined heat fluxes in the Gladis facility. The primary aim was to examine uncertainties in the determination of heat fluxes derived from IR-thermography during operation of W7-AS. It is found that the derived heat flux profiles are strongly influenced by the local distribution of plasma-deposited contamination analyzed by AES and SIMS. With the observed actual surface conditions characterized by redeposited contamination equivalent up to about 1 µm thickness, the heat fluxes were partially overestimated up to a factor of 4 during operation of W7-AS. This uncertainty is observed to be significantly reduced after heat treatment at temperatures beyond 700 o C attained at power flux densities of 10.5 MW/ m 2 and durations longer than 5 seconds.