Abstract:We have investigated the growth of polythiophene from self-assembled monolayers (SAMs) that contain pendant thiophene groups using electrochemistry and atomic force microscopy. The SAMs are formed on indium tin-oxide (ITO) by coadsorption of 11-(3-thienyl)undecyltrichlorosilane (3TUTS) and undecyltrichlorosilane (UTS). By altering the composition of the underlying monolayers we can manipulate the onset of electrochemical polymerization and affect the surface topography of the resultant polythiophene layer. Fil… Show more
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