We report on a new character of single domain wall (DW) of electrically-poled ferroelectric crystal which can modulate parametric processes via Cherenkov-type phase matching. Experimental result shows that the effective nonlinear polarization is confined in DW, and its phase velocity can be modulated when incident light is off the domain wall's direction. These effects lead to novel Cherenkov second harmonic generation (CSHG), and other modulated parametric process, such as Cherenkov sum frequency generation (CSFG).