“…However, the highest values for discharge voltage, main capacitance and repetition rate, implying stable glow discharges in SPA pre-ionized active volume, do not exceed 31 kV, 33.3 nF and 1 Hz, respectively. This behavior can be explained based on some structural and physical differences between these pre-ionization systems as follows: (a) Due to the geometry condition, the UV radiation produced by the patterned PCB covers the discharge volume more efficiently and effectively than that is emitted by the array of the peripheral spark gaps; (b) the uniform surficial plasma created on the PCB can provide additional help to glow discharge by growing towards the anode electrode; (c) in contrast to the high-density lowenergy electrons generated in spark discharges which are very efficient in dissociating CO 2 molecules through vibrational excitation, the low-density high-energy electrons produced in surface discharges are not so effective in dissociation of CO 2 molecules through vibrational as well as electronic excitations [16]; (d) these high-energy electrons shift the spectrum of the relevant radiation towards the UV region suitable for photoionization of the CO 2 lasers gas mixtures, thereby creating higher photo-electron densities in the active volume than those produced by the spark-induced radiation [20].…”