ZnO nanorods have been prepared with sol–gel methods using zinc acetate dihydrate in
ethanol in the presence of lithium hydroxide via alkaline hydrolysis. The electron transfer
behaviour at the surface and interface in ZnO nanorods was investigated by means of the
surface photovoltage technique. The influence of adsorbed oxygen on the surface
photovoltage (SPV) response of ZnO nanorods was studied by surface photovoltage
spectroscopy (SPS) and field-induced surface photovoltage spectroscopy (FISPS). The
results of SPS demonstrate that for ZnO nanorods the built-in electric field should be a
main driving force for the separation of the photogenerated electron–hole pairs and its
ensuing SPV response. The method of photogenerated charge recombination was also
studied with the aid of PL spectroscopy. It is shown that the two methods of energy
relaxation in light-excited ZnO nanorods are competitive. When oxygen is adsorbed at the
surface and the built-in electric field is formed, the SPV response should be the leading
one. Nevertheless, when oxygen is absent, the energy relaxation is mostly carried out by
radiative emission.