Abstract:<p>Surface
states—the electronic states emerging as a solid material terminates at a
surface—are usually vulnerable to contaminations and defects. This fundamental
limitation has prohibited systematic studies of the potential role of surface
states in surface reactions and catalysis, especially in more realistic
environments. Herein, we use selective hydrogenation of <a>cinnamaldehyde</a>
(CAL) on <a>platinum-covered titanium oxide</a> (Pt@P25) as
a prototype reaction, and show th… Show more
Generally, the catalytic transformation of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) at heterogeneous metal surface follows a Langmuir-Hinshelwood (L-H) mechanism when sodium borohydride (NaBH4) is used as the sacrificial reductant. Herein,...
Generally, the catalytic transformation of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) at heterogeneous metal surface follows a Langmuir-Hinshelwood (L-H) mechanism when sodium borohydride (NaBH4) is used as the sacrificial reductant. Herein,...
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