Surface‐Modified Carbon Materials for CO₂ Electroreduction

Abstract

The electrochemical reduction of CO2 to produce sustainable fuels and chemicals has attracted great attention in recent years. It is shown that surface‐modified carbons catalyze the CO2RR. This study reports a strategy to modify the surface of commercially available carbon materials by adding oxygen and nitrogen surface groups without modifying its graphitic structure. Clear differences in CO2RR activity, selectivity and the turnover frequency between the surface‐modified carbons were observed, and these differences were ascribed to the nature of the surface groups chemistry and the point of zero charge (PZC). The results show that nitrogen‐containing surface groups are highly selective towards the formation of CO from the electroreduction of CO2 in comparison with the oxygen‐containing surface groups, and the carbon without surface groups. This demonstrates that the selectivity of carbon for CO2RR can be rationally tuned by simply altering the surface chemistry via surface functionalization.

Mass transport effects in gas-phase selective hydrogenation of 1,3-butadiene over supported Pd

“…It was shown before that this carbon material is effective in (selective) oxidation and hydrogenation reactions. 21,40–43 In short, 2 g of carbon was dried under a dynamic vacuum at 180 °C for 1 hour. Subsequently, a Pd-precursor solution with a volume equal to support pore volume (0.8 cm 3 g −1 ) was added dropwise to the dried carbon material.…”