Surface modification of polymeric microspheres using glycopolymers for biorecognition

Pfaff, André; Barner, Leonie; Müller, Axel H. E.; Granville, Anthony M.

doi:10.1016/j.eurpolymj.2010.09.020

Cited by 47 publications

(44 citation statements)

References 52 publications

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“…Many of the functional styrenes in Fig. 9 have been used to prepare polymers for optoelectronic 318 [166] 319 [231] 320 [222] 321 [232] 322 (X ϭ H, F, OCH 3 ) [204] 323 [233] 324 [189] 325 [580] 326 [249] 327 n ϭ1 [234] 328 n ϭ 4 [ …”

Section: Styrenicsmentioning

confidence: 99%

“…[166] [420] NIPAm-b-DMAm [420] Thiol-ene Cellulose 156 EA [629] NIPAm [629] DCC/DMAP PLA Poly(MMA-co-TMSEMA) 136 NIPAm [630] Alkyne-azide 'click' C Poly(TMSEMA) 226 VAc [631] DCC/DMAP C Loprodyne (hydroxylated nylon-6,6 membrane) 121 NIPAm [382] DIC/DMAP Polypropylene 89 AA [632] AA-b-Am [632] UV initiator grafted to surface, used in AA polymerization in presence of 89. Am grafted Divinylbenzene microspheres 11 312 [166] RAFT agent attached by single unit monomer insertion. [466] Am [466] Active ester-amine poly(PSt/MAH) breath figure 179 NIPAm [464] NIPAm/372 [464] Acid chloride Graphene oxide 123 NVC [633] DCC/DMAP A RAFT agent used to modify the surface.…”

Section: Grafting-from Processesmentioning

confidence: 99%

“…[518] The use of thiol-ene chemistry to attach a glycopolymer to divinylbenzene microspheres. [166] RAFT-synthesized PAA (co)polymers as dispersants in preparing CdS quantum dot nanocomposites. [325] The use of the thiocarbonyl hetero-Diels Alder reaction to couple poly(iBA) (formed with 57) to cyclopentadienefunctional cellulose.…”

Section: Grafting-to Processesmentioning

confidence: 99%

“…S S * BzMA [161] MMA [162] PEGMA [163] 302 [164] 301 [165] 312 [166] 396 [167] MA [168] PFPVB [169] PVS [169] St [132,162] 359 [170] St [171] BA [122] MMA/BDSMA [172] (MAA/TPMMA) [173] (MAA/293) [173] DEGMA/PEGMA [174] tBMA/DMAEMA/290 [175] MMA/LMA [163] 396-b-PEGMA [167] St/AcS [176] 4VP/EGDMA [177] (St-b-DMAEMA) [171] BzMA-b-HPMAm [161] DEGMA/PEGMA-b-DMAPMAm [174] PEGMA-b-MMA [163] LMA/MMA-b-PEGMA [163] 12 S S CN D* [178] MMA [178][179][180][181][182][183][184] PEGMA [111,185] GMA [186] 289 [186,187] 297 [188] 324 [189] 453 [190] iPOx [191] St [132,…”

mentioning

confidence: 99%

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Living Radical Polymerization by the RAFT Process – A Third Update

2012

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This paper provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(¼S)SR) by a mechanism of reversible addition-fragmentation chain transfer ( Chem. 2009Chem. , 62, 1402. This review cites over 700 publications that appeared during the period mid 2009 to early 2012 covering various aspects of RAFT polymerization which include reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses, and a diverse range of applications. This period has witnessed further significant developments, particularly in the areas of novel RAFT agents, techniques for end-group transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

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Section: Styrenicsmentioning

confidence: 99%

Section: Grafting-from Processesmentioning

confidence: 99%

Section: Grafting-to Processesmentioning

confidence: 99%

mentioning

confidence: 99%

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Living Radical Polymerization by the RAFT Process – A Third Update

2012

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“…The process of grafting to polymer surface is one way of the permanent functionalization of polymeric particles. Covalent attachment of organic parts onto a polymer surface assures the long-term chemical stability of introduced chains, in contrast to physically coated polymer chains [12][13][14]. Most stationary phases currently used for separation of ionic compounds are based on organic polymers as well as silica gel.…”

Section: Introductionmentioning

confidence: 99%

Thermal characterization of polymeric anion exchangers with a dendrimeric structure

Grochowicz

Gawdzik

Jaćkowska

et al. 2013

J Therm Anal Calorim

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The thermal properties of new anion exchangers prepared via the grafting process to polymeric particles having hydroxyl groups on their surface were evaluated by thermogravimetry and differential scanning calorimetry. The support microspheres were copolymers of 1,4-di (2-hydroxy-3-methacryloyloxypropoxy)benzene (1,4 DMH) and trimethylolpropane trimethacrylate (TRIM). They were coated with polymeric layers formed by condensation polymerization of primary amines with diepoxides. Synthesized copolymers of methylamine and 1,4-butanedioldiglycidyl ether have a dendrimer structure. By TG/FTIR/ MS, it was observed that new dendrimeric materials exhibited one stage of mass loss with T max1 400°C, connected with degradation of organic layers. DSC and TG experiments showed that water molecules are absorbed on the materials surface. The synthesized anion exchangers exhibited good thermal stability, suitable for their use in chromatographic experiments carried out with higher temperatures.

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Synthesis and Application of Glycopolymers

Babiuch

Stenzel

2014

Encyclopedia of Polymer Science and Technology

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Multimeric representations of carbohydrates play a pivotal role in many biological processes. Polymer chemists aim at copying these biologically active biopolymers by the design of glycopolymers, synthetic polymers with pendant sugars. This article is focused on the synthetic methods as well as applications of these macromolecules. Since the first description of glycopolymers in the late 1950s, a myriad of glycopolymer structures have been reported. The first glycopolymer was prepared via free radical polymerization, but soon other techniques including ionic chain polymerization, ring‐opening polymerization, and ring‐opening methatesis polymerization followed. The arrival of living radical polymerization techniques caused a surge in publications on glycopolymers. Although most polymerization techniques have been employed to create glycopolymers, atom‐transfer radical polymerization and reversible addition‐fragmentation chain transfer (RAFT) polymerization dominate the literature. Architectures reported range from simple homopolymers to block copolymers, endfunctional glycopolymers, and stars and gels. Immobilization of initiators or RAFT agents led to bioactive surfaces. In recent years, the focus has shifted from the pure interest in the synthesis to the investigation of the biological activity of these glycopolymers. While the direct synthesis using glycomonomers dominated the literature for years, recent times saw the increased use of postmodification procedures. Reactive polymers were conjugated with sugars using an array of reactions including click chemistry and various reactions based on thiol‐ or amino sugars. This article gives a brief historical account on the synthesis of glycopolymers and outline briefly the different techniques—direct synthesis and postmodification—to design glycopolymers. The main focus will be, however, the advancements in applications of glycopolymers since around 2010, which contributed to the existing knowledge on how the structure of the glycopolymer affects the binding with lectin.

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Surface modification of polymeric microspheres using glycopolymers for biorecognition

Cited by 47 publications

References 52 publications

Living Radical Polymerization by the RAFT Process – A Third Update

Living Radical Polymerization by the RAFT Process – A Third Update

Thermal characterization of polymeric anion exchangers with a dendrimeric structure

Synthesis and Application of Glycopolymers

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