Surface Modification of Ferritic Stainless Steel by Heating in Iron, Graphite and Alumina Powders

Abstract

A new surface modification technique, called "iron-powder pack (IPP) treatment", has been proposed. During IPP treatment, carbon and nitrogen diffuse into a metal substrate by treating it with a mixture of iron and carbon powders at high temperature in a nitrogen flow. This paper describes the effects of adding alumina to the mixture of iron and graphite powders on the microstructures and hardness of SUS430 ferritic stainless steel after IPP treatment. The alumina powder was added to prevent powder mixtures from sintering. A 7:3 (volume ratio) mixture of iron and graphite powders was used as a "base powder", and the volume ratio of the alumina powder added to the base powder was varied from 0:1 to 50:1. A steel pipe packed with SUS430 steel and powder was heat-treated at 1 273 K for 3.6 ks in a nitrogen flow and then rapidly cooled in water. A surface-modified layer formed on the SUS430 steel through IPP treatment. When IPP treatment was performed using only the base powder, carbon was detected in the surface-modified layer. Both carbon and nitrogen diffused when alumina was added to the base powder. However, the thickness of the surface-modified layer gradually decreased from 380 to 125 μm with an increase in the amount of alumina. A similar tendency was observed in the surface hardness of the steel. In addition, the effects of subzero treatment and immersion in an aqueous nitric acid solution on the modified steel are discussed.

Novel Solid Carburizing Method for Steel Using a Mixture of Iron and Graphite Powders

“…To solve the problem, alumina powder is generally added to the iron and graphite powders as an anti-sintering agent. 13)…”

“…When alumina powder is added as a reliable anti-sintering agent to a mixture of iron and graphite powders, both carbon and nitrogen diffuse into the steel. 13) We have named such a surface modification technique "iron-powder pack (IPP) treatment". It has been confirmed that the iron powder acts as an important agent for enhancing the diffusion of carbon from the powder mixture to the specimen.…”