2023
DOI: 10.1016/j.ijhydene.2023.01.072
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Surface modification of Co3O4 nanostructures using wide range of natural compounds from rotten apple juice for the efficient oxygen evolution reaction

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Cited by 9 publications
(5 citation statements)
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“…O Lat represents lattice oxygen in a metal–oxygen structure, O Sur is usually assigned to surface defects and oxygen vacancies, and O Che is assigned to chemisorbed oxygen, as revealed by previous studies. 44 By quantifying the different oxygen species in both samples, the O Sur /O Lat ratio changes from 0.52 to 0.76 from pure NiCo 2 O 4 to sample 2, indicating that there is a greater proportion of surface species in the latter sample that could play an important role in the OER reaction. The detailed XPS peak attributions for pure NiCo 2 O 4 and sample 2 are given in Table S2 †…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…O Lat represents lattice oxygen in a metal–oxygen structure, O Sur is usually assigned to surface defects and oxygen vacancies, and O Che is assigned to chemisorbed oxygen, as revealed by previous studies. 44 By quantifying the different oxygen species in both samples, the O Sur /O Lat ratio changes from 0.52 to 0.76 from pure NiCo 2 O 4 to sample 2, indicating that there is a greater proportion of surface species in the latter sample that could play an important role in the OER reaction. The detailed XPS peak attributions for pure NiCo 2 O 4 and sample 2 are given in Table S2 †…”
Section: Resultsmentioning
confidence: 99%
“…The photoelectron contributions for the Co 2p 3/2 signal of pure NiCo 2 O 4 were observed at 779.5 (Co 3+ ), 781.4 (Co 2+ ), 784.2 (satellite) and 788.9 (satellite) eV, which is in good agreement with the reported works. [44][45][46] Similarly, the Ni 2p 3/2 contributions were located at different binding energies of 854.0 (Ni 2+ ), 855.7 (Ni 3+ ), 857.0 (Ni-OH) and 861.1 (satellite) eV. 47 The relative ratio of Ni 2+ /Ni 3+ ions and Co 2+ /Co 3+ ions in pure NiCo 2 O 4 was found to be 1.13 and 0.44, respectively.…”
Section: Physical Characterization Of As-prepared Different Nico 2 O ...mentioning
confidence: 99%
“…Essentially, the equivalent circuit consisted of the constant phase element (CPE), charge transfer resistance ( R ct ), and solution resistance ( R s ). 31,57 In Table 2, we present the estimated values for charge transfer resistance. In comparison with other materials reported in this work, sample-2 had the lowest charge transfer resistance, which confirms that palladium incorporation into MoS 2 has enhanced sample-2's electrical conductivity, which has further contributed to the efficient operation of OERs.…”
Section: Resultsmentioning
confidence: 99%
“…However, there was only a significant difference observed between O-Co-O and Co-O metal oxide peaks at 667 cm -1 and 577 cm -1 , respectively [58,59]. FTIR studies indicated that higher concentrations of potassium chromate resulted in a decrease in metal oxide peaks, which indicates in situ growth of CrO0.87 and Co3O4.…”
Section: Crystal Quality Morphology and Surface Chemical Composition ...mentioning
confidence: 92%