We report the synthesis and characterization of a 2D semiconductive and photoconductive coordination polymer. [Zn(TPPB)(Cl2)]·H2O (1) (TPPB = N1,N1,N4,N4-tetrakis(4-(pyridin-4-yl)phenyl)benzene-1,4-diamine) consists of TPPB redox-active linker with bis(triarylamine) as a core. It...