Abstract:More than half of the world is fed and fueled through the Haber-Bosch process, and ammonia consumption and global population continue to grow in tandem. However, resulting nitrogen oxyanion (NOx) waste threatens aquatic ecosystems by feeding harmful algal blooms. Molecular transition metal electrocatalysts are poised to selectively reduce these NOx waste products: macrocyclic complexes are particularly robust to electrocatalytic N–O bond activations. Here, two cobalt-based macrocycles with redox-active ligand … Show more
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