2006
DOI: 10.1016/j.cis.2006.05.002
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Surface activity coefficients of spread monolayers of behenic acid salts at air–water interface

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Cited by 25 publications
(12 citation statements)
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“…1 it can be expected that the activity of each alcohol in the surface monolayer, determined from Eq. 12 on the assumption that the molar area does not depend on the type of alcohol (1.26 × 10 5  m 2 ·mol −1 ) [34] and its concentration, should be the same as that calculated from the following equation [40]:where π is the difference between water and aqueous solution surface tensions, and π max is the difference between the water and alcohol surface tensions.…”
Section: Resultsmentioning
confidence: 99%
“…1 it can be expected that the activity of each alcohol in the surface monolayer, determined from Eq. 12 on the assumption that the molar area does not depend on the type of alcohol (1.26 × 10 5  m 2 ·mol −1 ) [34] and its concentration, should be the same as that calculated from the following equation [40]:where π is the difference between water and aqueous solution surface tensions, and π max is the difference between the water and alcohol surface tensions.…”
Section: Resultsmentioning
confidence: 99%
“…In the case of solution of ''pure" alcohol it is possible to establish the surface activity coefficient f S 2 À Á basing on the analogous form of the Raoult's law for the surface plane of the monolayer phase, which can be written as [34]:…”
Section: Concentration Of Alcohol and Tx-100 At The Solution-air Intementioning
confidence: 99%
“…On the basis of this concentration for surfactant and alcohol per unit of area it is possible to determine the composition of the surface layer, namely the molar fraction of surfactant 1 (X S 1 ) and alcohol (X S 2 ) forming 1 m 2 surface plane using the equations [47] C ðrÞ 0 NA 0 þ C ðrÞ SL;1 NA 1 þ C ðrÞ SL;2 NA 2 ¼ 1; ð14Þ…”
Section: Adsorption At Ptfe-water and Pmma-water Interfacesmentioning
confidence: 99%