Sur la reactivite de gem-bromonitroalcanes en presence de thiolates.

Amrollah-Madjdabadi, A.; Beugelmans, R.; Lechevallier, A.

doi:10.1016/s0040-4039(00)96554-7

Cited by 10 publications

(3 citation statements)

References 9 publications

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“…Alternative methods for the synthesis of 3 have been reported and include homocoupling of the 5‐bromo‐5‐nitro derivative of 2 in the presence of tert ‐butyl thiol,10 and the use of an S RN 1 substitution reaction to provide the product in 30–50 % yield 11–13. Other methods have also been reported 14.…”

Section: Methodsmentioning

confidence: 99%

Synthesis of an Energetic Nitrate Ester

et al. 2008

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Ein gießfähiger Explosivstoff? Der hochenergetische Nitratester 1 wurde in einem Dreistufenprozess in guten Ausbeuten synthetisiert. Experimente und Rechnungen belegen ein ähnliches Zersetzungs‐ und Explosionsverhalten wie für andere, gut charakterisierte Explosivstoffe. 1 hat eine Dichte von 1.917 g cm−3 und einen Schmelzpunkt von 85–86 °C, was eine Verarbeitung durch Schmelzgussverfahren ermöglichen könnte.

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Section: Methodsmentioning

confidence: 99%

Synthesis of an Energetic Nitrate Ester

et al. 2008

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“…Alternative methods for the synthesis of 3 have been reported and include homocoupling of the 5-bromo-5-nitro derivative of 2 in the presence of tert-butyl thiol, [10] and the use of an S RN 1 substitution reaction to provide the product in 30-50 % yield. [11][12][13] Other methods have also been reported.…”

mentioning

confidence: 99%

Synthesis of an Energetic Nitrate Ester

et al. 2008

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Going out with a bang! A high‐energy‐density nitrate ester 1 with unique properties was synthesized in good yield in a three‐step process. Destructive stimuli studies and explosive performance calculations show that 1 has similar performance properties to those of well‐characterized explosives. 1 has a density of 1.917 g cm−3 and a melting point of 85–86 °C, which may lead to high‐performance melt‐castable applications.

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“…Further evidence for our initially proposed mechanism has been reported for the reactions between α-bromo nitro compounds and thiolates in a synthetic protocol. 30 Experimental General DMF and DMSO were distilled at reduced pressure from calcium hydride and stored over molecular sieves. Methanol was dried using magnesium and iodine.…”

Section: Reactions Between 2-substituted-2-nitropropanes and Thiolate...mentioning

confidence: 99%