Supramolecularly modulated carbon-centered radicals: toward selective oxidation from benzyl alcohol to aldehyde

Tang, Xingchen; Mei, Shan; Xu, Jiang-Fei; Zhang, Xi

doi:10.1039/d4cc01240b

Chem. Commun.

2024

DOI: 10.1039/d4cc01240b

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Supramolecularly modulated carbon-centered radicals: toward selective oxidation from benzyl alcohol to aldehyde

Xingchen Tang,

Shan Mei,

Jiang-Fei Xu

et al.

Abstract: The reactivity of ketyl radicals and benzoyl radicals, two key intermediates of photo-induced oxidation of benzyl alcohol, can be stabilized by the host-guest interaction of radicals with cucurbit[7]uril. As a...

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Supramolecularly modulated carbon-centered radicals: toward selective oxidation from benzyl alcohol to aldehyde

Abstract: The reactivity of ketyl radicals and benzoyl radicals, two key intermediates of photo-induced oxidation of benzyl alcohol, can be stabilized by the host-guest interaction of radicals with cucurbit[7]uril. As a...

Cited by 2 publications

References 50 publications

A simple method to modulate the selectivity of aryl azide photolysis using cucurbit[8]uril

A simple method to modulate the selectivity of aryl azide photolysis using cucurbit[8]uril

A cucurbit[8]uril-mediated host–guest complex for red-light photocatalysis

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