Abstract:Flexible 1,5-bis(salicilydene)carbohydrazone ligand in combination with an in situ formed divanadium [V2O3] 4+ core afforded one discrete tetranuclear complex and two polymeric chain-like architectures, mutually related as supramolecular isomers. The occurrence of a particular isomer was controlled through the reaction conditions. All isolated products were structurally characterized via X-ray diffraction and infrared spectroscopy, while the relative stability of the architectures was assessed via competitive … Show more
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