Supramolecular Interaction Modulation in Thermosensitive Composites: Enantiomeric Recognition and Chiral Site Regeneration
Wenbei Chen,
Xin Qiu,
Yuting Chen
et al.
Abstract:Herein, a novel strategy was implemented to modulate the supramolecular interaction between enantiomers and chiral recognition sites (CRSs), effectively resolving the issue of CRS saturation. Randomly methylated-β-cyclodextrin (Rm-β-CD) was used as the CRS (host molecule), and polymerized ionic liquids [poly ([vbim]TFSI)] were used as the supramolecular modulator (guest molecule), which self-assembled to generate thermosensitive supramolecular host/guest complexes. The enantiomeric binding capacity and enantio… Show more
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