Supramolecular Chirality in Azobenzene-Containing Polymer System: Traditional Postpolymerization Self-Assembly Versus In Situ Supramolecular Self-Assembly Strategy

Abstract

Recently, the design of novel supramolecular chiral materials has received a great deal of attention due to rapid developments in the fields of supramolecular chemistry and molecular self-assembly. Supramolecular chirality has been widely introduced to polymers containing photoresponsive azobenzene groups. On the one hand, supramolecular chiral structures of azobenzene-containing polymers (Azo-polymers) can be produced by nonsymmetric arrangement of Azo units through noncovalent interactions. On the other hand, the reversibility of the photoisomerization also allows for the control of the supramolecular organization of the Azo moieties within polymer structures. The construction of supramolecular chirality in Azo-polymeric self-assembled system is highly important for further developments in this field from both academic and practical points of view. The postpolymerization self-assembly strategy is one of the traditional strategies for mainly constructing supramolecular chirality in Azo-polymers. The in situ supramolecular self-assembly mediated by polymerization-induced self-assembly (PISA) is a facile one-pot approach for the construction of well-defined supramolecular chirality during polymerization process. In this review, we focus on a discussion of supramolecular chirality of Azo-polymer systems constructed by traditional postpolymerization self-assembly and PISA-mediated in situ supramolecular self-assembly. Furthermore, we will also summarize the basic concepts, seminal studies, recent trends, and perspectives in the constructions and applications of supramolecular chirality based on Azo-polymers with the hope to advance the development of supramolecular chirality in chemistry.

Biomimetic and Biological Nanoarchitectonics

“…In general, the creation of functional materials has been pursued using the more orthodox methodologies of organic chemistry [ 7 , 8 , 9 ], inorganic chemistry [ 10 , 11 , 12 ], supramolecular chemistry [ 13 , 14 , 15 ], coordination chemistry [ 16 , 17 , 18 ], polymer chemistry [ 19 , 20 , 21 ], and other material sciences [ 22 , 23 ]. It has gradually become clear that functionality depends not only on the properties of the substance itself, but also on how its structure is controlled and how its components are arranged.…”

Recent developments in the chiroptical properties of chiral plasmonic gold nanostructures: bioanalytical applications

“…Chirality is a fascinating property of certain objects in nature [1]. Chirality means handedness, is observed in snail shells, gourd tendrils, human hands and even spiral galaxies [2,3]. An object is said to be chiral if it is not superimposable on its mirror image [4].…”

Circularly Polarized Light‐Driven Supramolecular Chirality

“…Figure 2. a) Schematic of the mechanism for the formation of the helical structure of a side-chain azopolymer film induced by elliptically polarized light.Reproduced under terms of the CC-BY license [37]. Copyright 2020, the Authors.…”