Abstract:The interest in cluster chemistry
lies not only in the development
of new types of geometric structures but also in the higher-level
connectivity and assembly of clusters at the supramolecular level.
Here, we report a novel windmill-like Al10 cluster and
consider this geometrically unique cluster as an anionic node assembled
together with different cationic guests such as imidazolium and guanidinium.
These guests with different hydrogen-bond angles can help to obtain
a series of diverse hydrogen-bonding networ… Show more
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