Supramolecular chemistry at interfaces

Huisman, Bart-Hendrik; Veggel, van Frank C.J.M.; Reinhoudt, David N.

doi:10.1351/pac199870101985

Cited by 14 publications

(8 citation statements)

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“…Measurement of the sulfur binding energy showed two peaks (Fig. 7), which represent discrete energies of a thiol [40] and a sulfonate [41] groups at 163 and 168 eV, respectively.…”

Section: Xps Measurementsmentioning

confidence: 99%

Detection of uranium(VI) in aqueous solution by a calix[6]arene modified electrode

Becker

Tobias

Porat

et al. 2008

Journal of Electroanalytical Chemistry

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“…Measurement of the sulfur binding energy showed two peaks (Fig. 7), which represent discrete energies of a thiol [40] and a sulfonate [41] groups at 163 and 168 eV, respectively.…”

Section: Xps Measurementsmentioning

confidence: 99%

Detection of uranium(VI) in aqueous solution by a calix[6]arene modified electrode

Becker

Tobias

Porat

et al. 2008

Journal of Electroanalytical Chemistry

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“…The use of noncovalent interactions at the solid−liquid interface provides an efficient and effective means of controlling the physical and chemical properties of surfaces . The ability to regulate noncovalent interactions between the surface and the modifier is an important tool for controlling the selectivity of the adsorption process.…”

Section: Introductionmentioning

confidence: 99%

Specific Hydrogen-Bond-Mediated Recognition and Modification of Surfaces Using Complementary Functionalized Polymers

et al. 2003

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Specific hydrogen-bonding interactions between polymers and surface-tethered recognition elements were used to selectively modify self-assembled monolayers (SAMs) on gold. The interfacial recognition processes were followed by observing frequency changes of thymine-SAM modified quartz crystal microbalance (QCM) chips during adsorption of diamidopyridine-functionalized (DAP) polystyrene from a nonpolar solvent. QCM studies combined with X-ray photoelectron spectroscopy (XPS), water contact angle, and ellipsometry measurements of the polymer-modified surfaces demonstrate the selectivity of the polymer-surface hydrogen-bonding interactions. These studies also indicate that the degree of recognition element functionalization of both the polymer and the surface is crucial in determining the rate, selectivity, and coverage of polymer on the surface.

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“…55 -56 A comparison of the response of the sulfide cavitand and octadecanethiol monolayers to organic vapours was measured by SPR spectroscopy. 24 ' 57 This indicated that each of the above vapours generally produced a response which was at least a factor of two greater for the cavitand monolayer. The only exception was C 2 C1 4 which produced a response twelve times greater for the cavitand monolayer.…”

Section: Binding Of Organic Amines From Aqueous Solution By Thin Filmmentioning

confidence: 97%

“…This result further supports guest/host molecular recognition of C2CI4 by the cavitand layer. 24 Crookes et al have demonstrated that/?-/er/-Bu-calix [4]arene 60 and p-tert-Bucalix [6]arene 61 attached to a reactive monolayer surface increased the adsorption Calixarenes in Action Downloaded from www.worldscientific.com by NANYANG TECHNOLOGICAL UNIVERSITY on 08/23/15. For personal use only.…”

Section: Binding Of Organic Amines From Aqueous Solution By Thin Filmmentioning

confidence: 99%

Calixarenes in Thin Film Supramolecular Materials

Lucke

Stirling

2000

Calixarenes in Action

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Calix[n]arenes have found new applications in the area of thin films . Thin films can be thought of as two dimensional supramolecular materials that are of both fundamental and industrial interest . Calix[n]arenes and resorcin[4]arenes can be deposited as thin films through a variety of techniques such as Langmiur-Blodgett, self-assembly , and evaporative methods. This chapter examines the physical properties of thin films and their interactions with their environment. In particular, thin films of calix[n]arenes and their adsorption of metal ions, molecular ions , and neutral organic molecules have become of great interest for use in new devices for sensing, nonlinear optics, pyroelectric and semiconductor applications. 8.1 Introduction Calix[n]arenes and resorcin[4]arenes (Figure 1) have become important molecules for the preparation of new supramolecular materials.14 These novel materials have been examined for purely fundamental interest but, often they have other potential applications. Central to their ongoing development as new supramolecular materials are their host-guest properties. Calix[n]arenes and resorcin[4]arenes have found applications in thin films, chromatography supports, polymers and catalysts. This review focuses on the preparation and application of thin films of calix[n]arenes and resorcin[4]arenes. OH Calix[n]arene R Resorcin[4]areneFigure 1. Generalised structures of calix[n]arenes and resorcin [4]arenes.172 Calixarenes in Action Downloaded from www.worldscientific.com by NANYANG TECHNOLOGICAL UNIVERSITY on 08/23/15. For personal use only.

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Supramolecular chemistry at interfaces

Abstract: Abstract

Cited by 14 publications

References 0 publications

Detection of uranium(VI) in aqueous solution by a calix[6]arene modified electrode

Detection of uranium(VI) in aqueous solution by a calix[6]arene modified electrode

Specific Hydrogen-Bond-Mediated Recognition and Modification of Surfaces Using Complementary Functionalized Polymers

Calixarenes in Thin Film Supramolecular Materials

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