2011
DOI: 10.1063/1.3658810
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Suppression of luminescence quenching at the nanometer scale in Gd2O3 doped with Eu3+ or Tb3+: Systematic comparison between nanometric and macroscopic samples of life-time, quantum yield, radiative and non-radiative decay rates

Abstract: International audienc

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Cited by 35 publications
(18 citation statements)
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“…This is the so-called concentration quenching effect. Similar quenching phenomenon has been reported in various rareearth doped phosphors, and differs for different rare-earth ions, hosts, structures, grain sizes and annealing temperatures [27]. The quenching effect of Eu 3+ ions has been considered to be contributed by Eu-Eu energy transfer, phonon-assisted dipole and multi-pole energy transfer [28].…”
Section: Resultsmentioning
confidence: 86%
“…This is the so-called concentration quenching effect. Similar quenching phenomenon has been reported in various rareearth doped phosphors, and differs for different rare-earth ions, hosts, structures, grain sizes and annealing temperatures [27]. The quenching effect of Eu 3+ ions has been considered to be contributed by Eu-Eu energy transfer, phonon-assisted dipole and multi-pole energy transfer [28].…”
Section: Resultsmentioning
confidence: 86%
“…In fact, the suspended nanoparticles are in a state of random movement (Brownian motion) due to thermal agitation and are allowed to interact with each other [10]. The RE oxide based phosphors are widely used in high-performance luminescent devices, catalysts, and other functional devices based on the electronic, optical, and optoelectronic features arising from the participation of 4f electrons [11,12].…”
Section: Introductionmentioning
confidence: 99%
“…To investigate the spectral distinction of lanthanide-doped NPPs for correlating CL and NIR, Tm 3+ /Yb 3+ , Ho 3+ /Yb 3+ , and Er 3+ /Yb 3+ ions were selected for the activator/sensitizer association in this work. An appropriate activator/sensitizer dopant concentration is one of the most important factors for getting the highest emission intensity at a distinct wavelength for NIR, as it is well known that the luminescence intensity depends on the sensitizer/activator concentration in NIR emissions [34,35,36]. The concentration quenching varies among the sensitizer/activator combinations.…”
Section: Introductionmentioning
confidence: 99%