Supported dichlorotriosmium clusters: Catalysts for olefin isomerization

Wolf, Martina; Liéto, J.; Matrana, B. A.; Arnold, D.B.; Gates, B. C.; Knözinger, Helmut

doi:10.1016/0021-9517(84)90284-7

P‐Donor LigandsBased in part on the article P‐Donor Ligands by Charles A. McAuliffe & Anthony G. Mackie which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Schier

¹

,

Schmidbaur

²

2005

Encyclopedia of Inorganic Chemistry

1

0

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Organophosphorus compounds of various types are among the most important classes of ligands in the coordination chemistry of the transition elements. This is particularly true for the tertiary phosphines R 3 P, which are known to stabilize complexes of metals in low oxidation states, while secondary and primary phosphines, R 2 HP and RPH 2 , are less common. The donor properties and the stereochemistry can be tuned by using carefully designed substitution patterns. More recently, organophosphorus compounds with low‐coordinate phosphorus atoms have also been employed as ligands in metal complexes. These include mainly phosphaalkenes and phosphaalkynes, phosphinidenes, diphosphenes, phosphinines, phosphonium cations, and even elemental phosphorus.

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P‐Donor LigandsBased in part on the article P‐Donor Ligands by Charles A. McAuliffe & Anthony G. Mackie which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Schier

¹

,

Schmidbaur

²

2005

Encyclopedia of Inorganic and Bioinorganic Chemistry

0

View full text Add to dashboard Cite

Organophosphorus compounds of various types are among the most important classes of ligands in the coordination chemistry of the transition elements. This is particularly true for the tertiary phosphines R 3 P, which are known to stabilize complexes of metals in low oxidation states, while secondary and primary phosphines, R 2 HP and RPH 2 , are less common. The donor properties and the stereochemistry can be tuned by using carefully designed substitution patterns. More recently, organophosphorus compounds with low‐coordinate phosphorus atoms have also been employed as ligands in metal complexes. These include mainly phosphaalkenes and phosphaalkynes, phosphinidenes, diphosphenes, phosphinines, phosphonium cations, and even elemental phosphorus.

show abstract

ChemInform Abstract: SUPPORTED DICHLOROTRIOSMIUM CLUSTERS: CATALYSTS FOR OLEFIN ISOMERIZATION

Wolf¹,

Liéto²,

Matrana³

et al. 1984

Chemischer Informationsdienst

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Supported dichlorotriosmium clusters: Catalysts for olefin isomerization

Cited by 13 publications

References 18 publications

P‐Donor LigandsBased in part on the article P‐Donor Ligands by Charles A. McAuliffe & Anthony G. Mackie which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

P‐Donor LigandsBased in part on the article P‐Donor Ligands by Charles A. McAuliffe & Anthony G. Mackie which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

P‐Donor LigandsBased in part on the article P‐Donor Ligands by Charles A. McAuliffe & Anthony G. Mackie which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

ChemInform Abstract: SUPPORTED DICHLOROTRIOSMIUM CLUSTERS: CATALYSTS FOR OLEFIN ISOMERIZATION

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