Supported copper (I) catalyst from fish bone waste: An efficient, green and reusable catalyst for the click reaction toward <i>N</i>‐substituted 1,2,3‐TRIAZOLES

Xiong, Xingquan; Tang, Zhongke; Sun, Zhao-Hong; Meng, Xianghe; Song, Sida; Quan, Zhilong

doi:10.1002/aoc.3946

Cited by 20 publications

(10 citation statements)

References 38 publications

(36 reference statements)

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“…In 2018, Xiong et al offered a new method to organize fishbone powder supported CuBr (FBPs/CuBr) and its utilization as an eco-efficient, stable, and separable catalyst in the MW irradiation assisted production of 1,2,3-triazoles (Scheme 9). 63 The catalyst can be removed easily by filtration and reused in seven successive runs.…”

Section: Applications Of Bone Waste-based Catalysts In Synthetic Orgamentioning

confidence: 99%

Low‐cost and sustainable (nano)catalysts derived from bone waste: catalytic applications and biofuels production

Nasrollahzadeh

Bidgoli

Shafiei

et al. 2020

Biofuels Bioprod Bioref

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The application of (bio)wastes as alternatives to expensive existing catalysts is an approach that can be used to reduce environmental pollution problems. Animal bone wastes have attracted much attention as environmentally friendly heterogeneous catalysts for chemical transformations such as transesterification, oxidation, and biofuel production, owing to the substantial availability of valuable hydroxyapatite (HAp) in their structure. Most catalysts based on bone can be prepared easily by calcination. High-temperature calcination yields highly active catalysts. Heterogeneous catalysts prepared from these renewable sources could also simply be reused and recovered without any important loss of catalytic performance. This paper reviews past efforts and recent progress on the development of different eco-friendly catalysts derived from bone waste and some of their catalyzed chemical transformations. However, future challenges focus on crediting the conversion of unusable wastes to valuable sources to meet global requirements

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Section: Applications Of Bone Waste-based Catalysts In Synthetic Orgamentioning

confidence: 99%

Low‐cost and sustainable (nano)catalysts derived from bone waste: catalytic applications and biofuels production

Nasrollahzadeh

Bidgoli

Shafiei

et al. 2020

Biofuels Bioprod Bioref

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“…Application of microwave irradiation and recyclable alumina-CuI catalyst in the multicomponent synthesis of 1H-1,2,3-triazole derivatives. 234 Recently, a multicomponent method involving propargyl bromide, amines and organic azides has been reported by Xiong et al 235 In this procedure, CuBr was supported on fish bone powder residue generating the catalyst FBPs-CuBr, which was efficient in the preparation of several N-substituted 1H-1,2,3-triazoles and could be reused for seven reaction cycles (Scheme 37). In addition, a scaling up to 40.0 mmol showed that the method has potential for industrial applications.…”

Section: Scheme 25mentioning

confidence: 99%

“…Use of FBPs-CuBr as a recyclable catalyst in the multicomponent synthesis of 1H-1,2,3-triazole derivatives. 235 3.3.7 Multicomponent CuAAC reactions. Multicomponent Reactions provide ideal approaches for synthesizing structurally simple or complex molecules in a few reaction steps and with excellent overall yields.…”

Section: Scheme 25mentioning

confidence: 99%

1,2,3- Triazoles: general and key synthetic strategies

Santos¹,

Oliveira²,

Oliveira³

et al. 2020

Arkivoc

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The applications of the 1H-1,2,3-triazole derivatives are particularly attractive and have received prominent attention in scientific research. The characteristics of these heterocycles motivated the development of different strategies for their preparation and molecular diversification. Most of the synthetic procedures available in the literature are based on catalysis with copper salts. Therefore, this review has as complementary central focus and updates the information about the properties and the main methods for the preparation of 1H-1,2,3-triazole derivatives, with emphasis on methods involving 1,3-dipolar cycloaddition between organic azides and terminal alkynes catalyzed by copper.

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“…In recent years, low‐cost and green synthesis of supported catalysts from biomass has attracted growing interest . In continuation of our efforts to develop green, highly efficient and practical chemical methods as well as a focus on the application of biomass‐based heterogeneous catalysts in organic reactions, we identified that Schiff base‐functionalized expanded corn starch‐supported CuBr (ECS‐SB‐CuBr) in the presence of TEMPO as a co‐catalyst was an efficient catalyst for promoting the selective aerobic oxidation of HMF into DFF under ambient pressure of dioxygen at 50°C in acetonitrile (Scheme ).…”

Section: Introductionmentioning

confidence: 99%

Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran

Min

et al. 2019

Applied Organom Chemis

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The development of new strategies for the synthesis of biomass‐based non‐precious metal heterogeneous catalysts has recently received great interest from chemists because of the advantages of these catalytic systems being sustainable, low cost and green. An expanded corn starch‐supported CuBr catalyst (ECS‐SB‐CuBr) has been successfully prepared and well characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, powder X‐ray diffraction, X‐ray photoelectron spectroscopy and scanning electron microscopy/energy‐dispersive X‐ray spectroscopy. Further, ECS‐SB‐CuBr was used as a heterogeneous catalyst for the selective oxidation of 5‐hydroxymethylfurfural (HMF) into 2,5‐diformylfuran (DFF) and a full HMF conversion is obtained with 98% DFF yield in acetonitrile under ambient pressure of dioxygen at 50°C. The catalyst also showed good reusability, could be easily recovered through filtration and washing and was reused in at least six consecutive runs with virtually no loss of catalytic performance.

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Supported copper (I) catalyst from fish bone waste: An efficient, green and reusable catalyst for the click reaction toward N‐substituted 1,2,3‐TRIAZOLES

Cited by 20 publications

References 38 publications

Low‐cost and sustainable (nano)catalysts derived from bone waste: catalytic applications and biofuels production

Low‐cost and sustainable (nano)catalysts derived from bone waste: catalytic applications and biofuels production

1,2,3- Triazoles: general and key synthetic strategies

Functionalized expanded corn starch‐anchored Cu(I): An efficient and recyclable catalyst for oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran

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