“…This suggests that the Al 8 Mn 5 phase has strong and coherent bonding with ␣-Mg, leading to a positive grain refining effect. Besides positive grain refining effect via heterogeneous nucleation, the addition of MnCO 3 provides an additional advantage, i.e., the melt agitation effect of carbon dioxide gas generated by reaction (2). As noted before, the majority of carbon dioxide gas reacts with the melt immediately after the decomposition of MnCO 3 , but the remaining gas is released into the air, accompanied with agitation of the melt.…”