“…Methyl‐6‐ O ‐( tert ‐butyldimethylsilyl)‐α‐ d ‐glucopyranoside (14 a) : White powder, 97 % yield (154 mg, 0.50 mmol); 1 H NMR ([D 7 ]DMF, 400 MHz): δ= 5.17 (d, J= 4.8 Hz, 1 H; OH‐C(4)), 5.08 (d, J= 4.5 Hz, 1 H; OH‐C(3)), 4.85 (d, J= 6.5 Hz, 1 H; OH‐C(2)), 4.80 (d, J= 3.4 Hz, 1 H; H‐C(1)), 4.12 (dd, J= 11.0, 2.1 Hz, 1 H; H‐C(6a)), 3.95 (dd, J= 11.0, J= 6.2 Hz, 1 H; H‐C(6b)), 3.78 (ddd, J= 4.5, 8.5, 3.8 Hz, 1 H; H‐C(3)) 3.67 (m, J= 3.8, 2.1, 4.8 Hz, 1 H; H‐(5)), 3.52 (s, 3 H; OCH 3 ), 3.50 (t, J= 3.8 Hz, 1 H; H‐C(2)), 3.44–3.38 (ddd, J= 4.5, 8.5, 5.1 Hz, 1 H; H‐C(4)), 1.08 (s, 9 H; H‐ t BuSi), 0.26 ppm (s, 6 H; H‐MeSi); the spectroscopic data for 14 a are in agreement with those data previously reported for this compound …”