Passive
daytime radiative cooling technology can cool objects without
any energy consumption. Although some progress has been made, there
are still challenges in manufacturing low-cost, anticontaminant, and
weathering-resistant radiative coolers for long-term cooling. Herein,
a superhydrophobic flexible cooling radiator (SFCR) as a film is fabricated
by a facile, inexpensive, and scalable electrospinning and electrospraying
method. The SFCR film consists of poly(vinylidene fluoride-co-hexafluoropropylene) fiber frameworks adhered to by numerous
microaggregates from SiO2 nanoparticles. The SFCR film
exhibited a strong solar reflectivity of 98.5% and an average emissivity
of more than 95%. It also showed superior superhydrophobicity and
wettability with a static water contact angle of 156° and sliding
angle of 2.2°. The average temperature drop of the film was 11.6
°C compared to the air around the film under sunlight. Importantly,
the self-cleaning effect of the SFCR film robustly protects its surface
against outdoor contamination and is conducive to sustainable cooling.
This SFCR film integrating radiative cooling with self-cleaning characteristics
is promising for scalable production and can be utilized on buildings,
vehicles, and other terrestrial objects.