Typical underwater piezoelectric spherical sensors are omni-directional, thus can measure the scalar quantity sound-pressure-magnitude only with the limitation not being able to measure the direction of the incoming wave. This paper proposes a method to simultaneously measure both the magnitude and direction of the sound wave with the spherical sensor. The method divides the piezoceramic sphere of the sensor into eight elements, and distinguishes the magnitude and direction of the sound pressure by combining the output voltage of the elements in a particular manner. Further, through the analysis of the sensitivity variation in relation to the structural parameters like radius and thickness of the piezoceramic sphere, we have suggested the way to improve the sensitivity of the vector sensor.