Abstract:Supercritical water oxidation (SCWO) reaction is effective in destruction of polychlorinated biphenyls (PCBs) to mineral products of CO 2 , HCl, and H 2 O such that 99.95% conversion of Aroclor 1248 is possible in 54.5 seconds residence time at 823 K and 25.3 MPa. Yet to design and operate SCWO reactors to avoid harmful products formation such as polychlorinated dibenzofurans and dioxins, it is necessary to understand the PCB reaction pathway leading to final products. This study shows the dechlorination react… Show more
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