Bulk single crystals of manganese phosphide (MnP) were grown from melt at 1 GPa and 1200 C by using a cubic-anvil, high-pressure, and high-temperature technique. The obtained black colored crystals exhibit a plate-like morphology, with flat surfaces and maximum dimensions up to 4 2 0.5 mm 3 . The orthorhombic crystal structure was confirmed by X-ray diffraction [Pnma, 62, Z = 4, a = 5.2510(4) Å, b = 3.1670(3) Å, c = 5.90098 (4) Å and V = 98.279(14) Å 3 ]. Temperature-dependent magnetization measurements reveal the occurrence of two successive transitions: a paramagnetic to ferromagnetic transition at T c = 290.5 K and the development of a double helimagnetic order at T s = 44.5 K. Zero-field 31 P NMR measurements in the FM and in the screw-spin AFM state show prominent features, which are compared with previous experimental data and theoretical calculations. The relatively large crystals obtained here open up new possibilities for further explorations of this interesting material.Recently, the evolution of the MnP magnetic state under high pressure was investigated via muon-spin spectroscopy [26]. These studies found that pressure suppresses rather quickly the helical state and reduces the T c of the FM transition. Furthermore an AFM-like phase seems to emerge above 1.5 GPa, successively completely disappearing above 8 GPa. All these transitions are characterized by coexisting FM and AFM phases, observed both as a function of temperature and pressure. The detailed structure of the new AFM order, which precedes the appearance of superconductivity, is still unclear and, hence, deserves further study.In order to understand the nature of the magnetic phase bordering with superconductivity,