“…[
13,18 ] Above all else, more than 20 superconducting compounds with the simple cubic AuCu 3 ‐type structure have been reported in the literature. [
2,7–9,16,26,28–31,34,35 ] Among them the ATl 3 systems became of interest initially because of their varied superconducting transition temperatures (
) that range from 0.87 to 2.04 K. [
2 ] ThTl 3 , YTl 3 , LaTl 3 , and CaTl 3 transform to superconductors at 0.87, 1.52, 1.63, and 2.04 K. Furthermore, the replacement La and Tl in LaTl 3 increases the
value from 1.63 to 8.86 K by more than five times. [
5 ] An interesting question is: why La 3 Tl have a much higher
than LaTl 3 ?…”