2008
DOI: 10.1143/jpsj.77.063707
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Superconductivity at 54 K in F-Free NdFeAsO1-y

Abstract: We have synthesized a series of oxygen-deficient, fluorine-free polycrystalline samples with nominal chemical formula NdFeAsO 1Ày using high-pressure technique. The ZrCuSiAs type crystal structure, as expected for NdFeAsO, is formed as the main phase for the composition 0 y 0:6. Sharp superconducting (SC) transition with their transition temperature (T c ) as high as 54 K is observed for 0:3 y 0:8 samples, which is higher than that of F-doped NdFeAsO. While T c does not depend on y, SC volume fraction shows ma… Show more

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Cited by 314 publications
(296 citation statements)
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“…Hole doping, by substituting Sr 2+ for La 3+ results in T c = 25 K [32]. A series of oxygen deficient RFeAsO 1-δ have also been prepared by high pressure syntheses with highest T c = 55 K for SmFeAsO 0.85 [33][34][35]. Here we report of the synthesis and characterization of Co-doped LaFeAsO, and find superconductivity for ~ 4 -12% doping levels.…”
Section: Introductionmentioning
confidence: 96%
“…Hole doping, by substituting Sr 2+ for La 3+ results in T c = 25 K [32]. A series of oxygen deficient RFeAsO 1-δ have also been prepared by high pressure syntheses with highest T c = 55 K for SmFeAsO 0.85 [33][34][35]. Here we report of the synthesis and characterization of Co-doped LaFeAsO, and find superconductivity for ~ 4 -12% doping levels.…”
Section: Introductionmentioning
confidence: 96%
“…Since the discovery of superconductivity in LaFeAs(O 1−x F x ) [1], high transition temperatures (T c ) up to 56 K have been reported in the doped Fe-based oxypnictides [2,3,4,5,6,7,8,9]. The new high-temperature superconductivity in Fe-pnictides has attracted tremendous interests both experimentally and theoretically.…”
Section: Introductionmentioning
confidence: 99%
“…2,3,4 In addition, recently, high temperature superconductivity with similar properties has been found in simpler compounds based on FeAs sheets such as ThCr 2 Si 2 structure type (Ba,K)Fe 2 As 2 . 5,6 These Fe-based materials are commonly viewed as unconventional (non-electron-phonon) superconductors based on the high values of T c , the proximity to magnetism and the fact that calculations of the electron phonon coupling show that it is far too weak to account for the superconductivity.…”
mentioning
confidence: 96%