“…A new compound, LaBaCaCu,O, with a critical temperature of 25K has been synthe~ized.,~ Further detailed investigation of the system La-Ba-Ca-Cu-0 allowed the preparation of three series with tetragonal triple perovskite structures and nominal compositions of La,-,Ca,Ba,Cu,O, A cadmium analogue of the T1 and Hg series, CdBa2Can-lCun02n+2+a, was obtained in ref. 44. The 1212 phase was found to be non-superconducting, but the substitution of Ca for Y [CdBa,(Ca,~,Y,~,)Cu,O,,] leads to superconductivity with T, = 103 K. 44 The 1223 phase has a critical temperature of 103-107 K.4s…”