Superchaotropic polyoxometalates as membrane carriers

Kondinski, Aleksandar

doi:10.26599/pom.2024.9140058

Polyoxometalates

2024

DOI: 10.26599/pom.2024.9140058

|View full text |Cite

Superchaotropic polyoxometalates as membrane carriers

Aleksandar Kondinski

Abstract: In the realm of pharmaceutical drug delivery and bioimaging, the innovative design of membrane transporters is crucial. This highlight article focuses on the recent collaborative study published in Advanced Materials

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 5 publications

References 35 publications

(44 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Nitrite Electroreduction Enhanced by Hybrid Compounds of Keggin Polyoxometalates and 1‐Butyl‐3‐Vinylimidazolium

Zhou,

Sun,

Gallet

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

We describe here an immobilization method of four Keggin‐type polyoxometalates (POMs) ([H2W12O40]6‐, [BW12O40]5‐ [SiW12O40]4‐, [PW12O40]3‐) by using the reaction with an ionic liquid, 1‐butyl‐3‐vinylimidazolium (BVIM) bromide. The reaction yields a hybrid material (BVIM‐POM) as a water‐insoluble salt. The chemical structure of both compounds is preserved, as indicated by infrared spectroscopy (FT‐IR), although with a reduced crystallinity (shown by X‐ray diffraction analysis) due to a decrease of water content (shown by thermogravimetric analysis). Cross polarization 1H‐31P NMR evidenced the presence of BVIM in the structure of (BVIM)3[PW12O40]. The salt is mixed with carbon powder and Nafion to prepare an ink and casted on glassy carbon electrodes. The electrochemical behavior of immobilized POMs material is preserved. The electrochemical activity for nitrite reduction is measured by cyclic voltammetry and differential electrochemical mass spectrometry (DEMS). It was observed that the reduction current of 10 mM HNO2 at pH 1 in 0.5 M Na2SO4 is enhanced in the presence of these hybrid materials. DEMS has evidenced the formation of nitrous oxide (N2O) at potentials more positive compared to the use of parent POMs in solution.

show abstract

Nitrite Electroreduction Enhanced by Hybrid Compounds of Keggin Polyoxometalates and 1‐Butyl‐3‐Vinylimidazolium

Zhou,

Sun,

Gallet

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

show abstract

Overview of Wells-Dawson Polyoxometalates: from structure and functionalization to application

Nowicka,

Vadra,

Wieczorek-Szweda

et al. 2024

Coordination Chemistry Reviews

View full text Add to dashboard Cite

Cylindrical HP^III-Sb^III-Templated Five-Layer Polyoxotungstate with Conspicuous Photochromism Triggered by UV or Visible Light

Zhang,

Liu

et al. 2024

Inorg. Chem.

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Superchaotropic polyoxometalates as membrane carriers

Abstract: In the realm of pharmaceutical drug delivery and bioimaging, the innovative design of membrane transporters is crucial. This highlight article focuses on the recent collaborative study published in Advanced Materials

Cited by 5 publications

References 35 publications

Nitrite Electroreduction Enhanced by Hybrid Compounds of Keggin Polyoxometalates and 1‐Butyl‐3‐Vinylimidazolium

Nitrite Electroreduction Enhanced by Hybrid Compounds of Keggin Polyoxometalates and 1‐Butyl‐3‐Vinylimidazolium

Overview of Wells-Dawson Polyoxometalates: from structure and functionalization to application

Cylindrical HP^III-Sb^III-Templated Five-Layer Polyoxotungstate with Conspicuous Photochromism Triggered by UV or Visible Light

Contact Info

Product

Resources

About

Superchaotropic polyoxometalates as membrane carriers

Abstract: In the realm of pharmaceutical drug delivery and bioimaging, the innovative design of membrane transporters is crucial. This highlight article focuses on the recent collaborative study published in Advanced Materials

Cited by 5 publications

References 35 publications

Nitrite Electroreduction Enhanced by Hybrid Compounds of Keggin Polyoxometalates and 1‐Butyl‐3‐Vinylimidazolium

Nitrite Electroreduction Enhanced by Hybrid Compounds of Keggin Polyoxometalates and 1‐Butyl‐3‐Vinylimidazolium

Overview of Wells-Dawson Polyoxometalates: from structure and functionalization to application

Cylindrical HPIII-SbIII-Templated Five-Layer Polyoxotungstate with Conspicuous Photochromism Triggered by UV or Visible Light

Contact Info

Product

Resources

About

Cylindrical HP^III-Sb^III-Templated Five-Layer Polyoxotungstate with Conspicuous Photochromism Triggered by UV or Visible Light