⁶³Cu NQR Studies of Two-and Three-coordinated Complexes of Cu(I) with Siloxyl Ligands

Abstract

We report the 63 Cu NQR spectra of seven two-and three-coordinated complexes with the siloxyl ligand. R 3 SiO~. The frequencies are compared to those of other two-and three-coordinated species, and it is demonstrated that the partial field gradient of the R 3 SiO~ group is very similar to that of CP.