2010
DOI: 10.1126/science.1180871
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238 U/ 235 U Variations in Meteorites: Extant 247 Cm and Implications for Pb-Pb Dating

Abstract: The 238U/235U isotope ratio has long been considered invariant in meteoritic materials (equal to 137.88). This assumption is a cornerstone of the high-precision lead-lead dates that define the absolute age of the solar system. Calcium-aluminum-rich inclusions (CAIs) of the Allende meteorite display variable 238U/235U ratios, ranging between 137.409 +/- 0.039 and 137.885 +/- 0.009. This range implies substantial uncertainties in the ages that were previously determined by lead-lead dating of CAIs, which may be … Show more

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Cited by 149 publications
(133 citation statements)
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“…Recent analytical advances leading to significantly greater precision along with renewed interest have led to several investigations of the U isotopic compositions of meteoritic materials in recent years. While refractory calcium-aluminum-rich inclusions (CAIs) in the carbonaceous chondrite Allende have been shown to have large variability in 238 U∕ 235 U ratios (3,5), the measured 238 U∕ 235 U ratios of bulk samples of several types of chondrites and achondrites are all within analytical uncertainty of one another, and have an average 238 U∕ 235 U ratio ≈ 137.78 (3-6, 20-22). There are many other meteorite types that have not yet been measured, but the current data suggest that while the 238 U∕ 235 U ratio of Solar System materials is resolvably distinct from the previously assumed value of 137.88, the extent of U isotopic variation among bulk meteorites is likely to be relatively small (i.e., smaller than the current level of precision of the U isotope measurements of AE1 − 2ε units).…”
Section: Discussionmentioning
confidence: 99%
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“…Recent analytical advances leading to significantly greater precision along with renewed interest have led to several investigations of the U isotopic compositions of meteoritic materials in recent years. While refractory calcium-aluminum-rich inclusions (CAIs) in the carbonaceous chondrite Allende have been shown to have large variability in 238 U∕ 235 U ratios (3,5), the measured 238 U∕ 235 U ratios of bulk samples of several types of chondrites and achondrites are all within analytical uncertainty of one another, and have an average 238 U∕ 235 U ratio ≈ 137.78 (3-6, 20-22). There are many other meteorite types that have not yet been measured, but the current data suggest that while the 238 U∕ 235 U ratio of Solar System materials is resolvably distinct from the previously assumed value of 137.88, the extent of U isotopic variation among bulk meteorites is likely to be relatively small (i.e., smaller than the current level of precision of the U isotope measurements of AE1 − 2ε units).…”
Section: Discussionmentioning
confidence: 99%
“…The residue remaining from this acid leaching (designated as "Residue") was completely dissolved using a mix of concentrated HNO 3 , HF, and HCl. Hand-picked phosphates (5.4 mg) from ADOR were provided by G. J. Wasserburg (Caltech) and were dissolved directly in 3 M HNO 3 . Approximately 5% of each dissolved sample used in this study was reserved for trace element measurements.…”
Section: Methodsmentioning
confidence: 99%
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“…Browne, Amelin et al (2005) for Richardton, and Bouvier et al (2007) for Nadiabondi & Kernouvé. We note that Pb-Pb age values were slightly revised upwards (by 1 Ma) according to recent revisions of the uranium isotopic ratio (Brennecka et al 2010).…”
Section: Thermochronological Datamentioning
confidence: 73%
“…The most accurate determinations of absolute ages of the oldest SS objects currently are based on Pb-Pb ages, because of the precision in the half-lives of the progenitors 235 U and 238 U and the coupled age data of isotope pairs. The adopted most pristine solids for this purpose, chondrules and CAIs, were considered to have invariant SS abundance ratios of these two progenitors, which turned out to be an incorrect assumption (Brennecka et al, 2010). The first combined high-precision U and Pb isotopic data for a CAI, and U isotopic data for chondrules and whole rock fractions of the Allende meteorite (Amelin et al, 2010) show that the Allende meteorite bulk rock and chondrules data have distinctly lower ratios ( 238 U/ 235 U=137.747) than the CAI.…”
Section: Time Of Formation Of the Solar System (Ss)mentioning
confidence: 99%