In this paper, we study the probability density function, P(c, α, β, n) dc, of the center of mass of the finite n Jacobi unitary ensembles with parameters α > −1 and β > −1; that is the probability that trM n ∈ (c, c + dc), where M n are n × n matrices drawn from the unitary Jacobi ensembles. We first compute the exponential moment generating function of the linear statistics n j=1 f (x j ) := n j=1 x j , denoted by M f (λ, α, β, n). The weight function associated with the Jacobi unitary ensembles reads x α (1 − x) β , x ∈ [0, 1]. The moment generating function is the n × n Hankel determinant D n (λ, α, β) generated by the time-evolved Jacobi weight, namely, w(x; λ, α,We think of λ as the time variable in the resulting Toda equations. The non-classical polynomials defined by the monomial expansion, P n (x, λ) = x n + p(n, λ) x n−1 + • • • + P n (0, λ), orthogonal with respect to w(x, λ, α, β) over [0, 1] play an important role. Taking the time evolution problem studied in Basor, Chen and Ehrhardt [5], with some change of variables, we obtain a certain auxiliary variable r n (λ), defined by integral over [0, 1] of the product of the unconventional orthogonal polynomials of degree n and n − 1 and w(x; λ, α, β)/x. It is shown that r n (2ie z ) satisfies a Chazy II equation. There is another auxiliary variable, denote as R n (λ), defined by an integral over [0, 1] of the product of two polynomials of degree n multiplied by w(x; λ, α, β)/x. Then Y n (−λ) = 1 − λ/R n (λ) satisfies a particular Painlevé V:The σ n function defined in terms of the λp(n, −λ) plus a translation in λ is the Jimbo-Miwa-Okamoto σ−form of Painlevé V. The continuum approximation, treating the collection of eigenvalues as a charged fluid as in the Dyson Coulomb Fluid, gives an