A modified sodium tetraphenyl-boron method (Na-TPB), which uses an incubation period and boiling with a copper solution to destroy the tetraphenyl-boron-K precipitate (TBK) instead of shaking and resolubilisation with acetone, is proposed as a replacement for Jackson's TBK method. The method as recommended is 1 g soil in 3 ml of 1.7 M NaCl/0.01 M EDTA solution + 0.2 g Na-TPB and incubated at 20°C for between 1 and 168 h. Testing of the method showed it to be a more rapid, accurate, and cost-effective means of routinely testing soil K reserves than Jackson's test. Correlation of TBK values against Jackson's method were good (r 2 = 0.88) for short extraction times (1-4 h) but decreased with increasing extraction time. Regressions of TBK values with K c values, the current method for differentiating K supplying ability between soils, were only fair (r 2 < 0.75). This was due to mechanistic differences between dissolution (Kc-acid extraction) and solubility based (TBK-precipitation) methods.Potassium release curves were established for a range of 24 New Zealand soils for 1-672 h. The bulk of K release (c. 80%) occurred for most soils within the first 48 h with release rates in significant decline after 168 h. Release curves were modelled using a range of simple kinetic models: empirical Elovich, power, exponential, simplified-Elovich, and parabolic diffusion equations were all examined. The quality of fit for each model tended to decrease in that order, although this varied between soil classes.