1983
DOI: 10.1524/ract.1983.33.1.29
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Sulfate Complexation of Np(V) in Aqueous Solution

Abstract: Np(V) sulfate /Aqueous complex /Stability constants AbstractThe stability constant of the monosulfate complex of Np(V) has been measured at ionic strengths of /= 0.5, 1.0 and 2.0 and at temperatures of 5, 25 and 45 °C. Entropy and enthalpy values for the process of complex formation have been shown to have relatively large positive values. Inner sphere complexing appears to be supported by these measurements.

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Cited by 22 publications
(20 citation statements)
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References 9 publications
(16 reference statements)
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“…For other filling QHE, several "deformed" Laughlin wavefunctions have been proposed as groundstates. Halperin wavefunction is a two-component extension of the Laughlin wavefunction and is introduced to formulate two-spin or bilayer QH liquids [6]. Especially, Halperin 331 state is believed to describe the bilayer QH liquid at ν = 1/2.…”
mentioning
confidence: 99%
“…For other filling QHE, several "deformed" Laughlin wavefunctions have been proposed as groundstates. Halperin wavefunction is a two-component extension of the Laughlin wavefunction and is introduced to formulate two-spin or bilayer QH liquids [6]. Especially, Halperin 331 state is believed to describe the bilayer QH liquid at ν = 1/2.…”
mentioning
confidence: 99%
“…The values of AH"' and AS"' at 25°C were calculated by using the Van't Hoff equation: aln p/a(i/~) = -AHO'R ; AS"' = (AH"'-AG"')/T (10) These calculated values are listed in Table 3 The activity of background: 1 cpm. The activity of background: 1 cpm.…”
Section: Effect Of Temperature On Stability Constantsmentioning
confidence: 99%
“…Sulfate, carbonate, and phosphate complexes can be important in actinide processing, and, along with silicates, are important ligands in determining the environmental behavior of actinide cations. Normally, the stability constants of the complexes with these ligands increase in the usual sequence of AnO (Halperin and Oliver, 1983). Stability constants for some actinide-sulfate complexes are summarized in Table 23.20.…”
Section: Complexes With Inorganic Ligandsmentioning
confidence: 99%
“…Sulfate complexes of uranyl(VI) can form polynuclear, ternary hydroxo-sulfato complexes in weakly acidic solutions (Grenthe and Lagerman, 1993;Moll et al, 2000). Choppin, 1967;Ahrland and Kullberg, 1971a;Halperin and Oliver, 1983;Nash and Cleveland, 1983;Martell et al, 1998) and carbonate complexes at I ¼ 0 M and 25 C (Grenthe et al, 1992;Silva et al, 1995;Lemire et al, 2001). Zielen, 1959;Jones and Choppin, 1969;Ahrland and Kullberg, 1971a;Halperin and Oliver, 1983 Carbonate complexes of the actinides have been investigated often, as reviewed by Newton and Sullivan (1985) and Clark et al (1995).…”
Section: Complexes With Inorganic Oxo Ligandsmentioning
confidence: 99%
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