Sterically crowded 5,10,15-triarylated truxenes are obtained by reaction of truxenetrione with aryllithium compounds (aryl = 1-naphthyl, 2-naphthyl, 9-phenanthryl, 9-anthracenyl), followed by reduction of the tertiary alcohols with (Figure 1) have received attention as potential starting materials for the construction of larger polyarenes [1Ϫ5] and for the synthesis of new materials.[6Ϫ9] For the synthesis of polyarenes with the topology of the fullerenes [10Ϫ12] we developed a synthesis of derivatives 3b by the reaction of the trianion of 1 with a variety of alkylating agents, followed by isomerization with KOtBu in tBuOH (Scheme 1). [13,14] Figure 1. Truxene (1) and truxenetrione (2) Scheme 1 [a]