Substituent Effects on Ring Opening Allene Metathesis: Polymerization Rate Enhancement and Regioregularity
William J. Neary,
Fengyue Zhao,
Megan C. Murphy
et al.
Abstract:Polyallenamers represent an emerging class of polymeric materials with highly tailorable and adaptive properties. While their generation has been achieved (via crosscoupling, postpolymerization modifications, and ring opening allene metathesis polymerization (ROAlMP)), molecular weight limitations and the inability to obtain precise microstructures have prevented the ability to utilize allenes to their full potential. Herein, we demonstrate the effects that allylic derivatization of cyclic allenes (4-R-1,2-CND… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.