Styrene-vinylferrocene random and block copolymers by TEMPO-mediated radical polymerization

Baumert, Martin; Fröhlich, Jörg; Stieger, Markus; Frey, Holger; Mülhaupt, Rolf; Plenio, Herbert

doi:10.1002/(sici)1521-3927(19990401)20:4<203::aid-marc203>3.0.co;2-i

Cited by 32 publications

(6 citation statements)

References 23 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…[90][91][92][93][94][95][96][97][98][99] In 1999, Frey and coworkers reported the copolymerization of vinylferrocene with styrene using the ''living'' radical initiator 2,2,6,6-tetramethyl-1-pyperidinyl-1-oxy (TEMPO). [100] These reactions resulted in the production of block copolymers with narrow polydispersities.…”

Section: Polymerization Of Olefin-functionalized Metallocenessupporting

confidence: 90%

Organometallic Polymers of the Transition Metals

Abd‐El‐Aziz

2002

Macromol. Rapid Commun.

164

View full text Add to dashboard Cite

This article provides a comprehensive review of the synthesis, properties and applications of organometallic polymers of the transition metals. The different classes of organometallic polymers are described according to their structural make‐up, as well as by their methods of synthesis. A number of examples of each class are given to emphasize the richness and diversity in these areas of research. In addition to linear polymers, hyperbranched, crosslinked, star and dendritic polymers are also described. The properties that transition metal‐containing organometallic polymers possess, as well as the applications that these materials have found in various domains are highlighted. magnified image

show abstract

Section: Polymerization Of Olefin-functionalized Metallocenessupporting

confidence: 90%

Organometallic Polymers of the Transition Metals

Abd‐El‐Aziz

2002

Macromol. Rapid Commun.

164

View full text Add to dashboard Cite

show abstract

“…This renders them very interesting in this field of science, and therefore the development of ferrocenyl-containing block-copolymers has become an important issue [7][8][9][10]. The corresponding methods developed by Nuyken et al and Frey et al are based on the controlled anionic and radical polymerization, respectively, and were successfully applied for the copolymerization of vinylferrocene with styrene or other olefinic monomers [11,12]. Balsara et al showed that a poly(vinylferrocene)-b-poly(isoprene) block-copolymer can be successfully applied as heterogeneous catalyst for Michael additions [13].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units

Armada¹,

Losada²,

López-Villanueva

et al. 2008

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

The electrochemical characterization of three different polystyrene-b-polybutadiene block-copolymers, functionalized with diferrocenylsilane units, is reported. The PB-blocks have been functionalized with different fractions of electronically communicated, PS m -PB" p (HSiMeFc 2 ) p units, where m = 615, n = 53, p = 39 (1), m = 375, n = 92, p = 76 (2) and m = 455, n = 204, p = 170 (3). Electrochemical characterization has been carried out both in solution and after electrochemical deposition onto platinum electrodes. The bioelectrocatalytical properties of electrodes modified with the polymers in the nicotinamide dinucleotide (NADH) and glucose oxidase (GOx) oxidations have been investigated as a function of the constitution and structure of the polymers. The analytical properties of electrodes modified with these polymers as sensors of NADH and GOx are described. In addition, an amperometric biosensor for glucose, prepared by electrostatic immobilization of glucose oxidase onto a platinum electrode modified with one of the ferrocenyl block-copolymers as an example, has been developed.

show abstract

“…Baumert et al employed TEMPO‐mediated free radical polymerization to synthesize a homopolymer of vinyferrocene and a copolymer of vinyferrocene with styrene, as shown in Scheme . Experimental results showed that molecular weight of the homopolymer of vinylferrocene was limited to 4.8 × 10 3 g mol −1 , while the molecular weight of the copolymer was up to 1.0 × 10 4 g mol −1 .…”

Section: Synthesis Of Ferrocene‐containing Polymers and Derivatives Umentioning

confidence: 99%

Progress on the synthesis and catalytic and anti‐migration properties of ferrocene‐based burning rate catalysts

Zhou

Wang

et al. 2016

Applied Organom Chemis

View full text Add to dashboard Cite

Burning rate catalysts are of great importance in solid composite propellants for their unique property of accelerating combustion speed. Among various kinds of burning rate catalysts, ferrocene and its derivatives exhibit excellent catalytic effects and have become the most widely used burning rate catalysts. However, these simple ferrocenyl compounds trend to migrate in solid composite propellants during storage, which causes great damage to the propellants, equipment and environment and can even affect personal safety. The exploration of novel anti‐migratory ferrocene‐based compounds has become an advanced research hotspot in the field of burning rate catalysis. This review focuses on recent progress on the synthesis and catalytic properties of ferrocene‐based polymers and ferrocene derivatives as burning rate catalysts. Two main aspects of anti‐migratory exploration, i.e. synthesis of ferrocene‐based polymers and modification of the side groups of ferrocene, are summarized. Ferrocene‐based polymers can be obtained via condensation polymerization, addition polymerization, ring‐opening polymerization, polymer reactions, etc. Ferrocenyl compounds with active groups and ferrocene‐based metal coordination compounds were developed instead of the methods of lengthening the carbon chain of side groups and improving molecular polarity. Also, possible mechanisms of burning rate catalytic activity and migration are discussed and analyzed. Finally, the key points of the development of ferrocene‐based burning rate catalysts and solid composite propellants are proposed. Copyright © 2016 John Wiley & Sons, Ltd.

show abstract

Styrene-vinylferrocene random and block copolymers by TEMPO-mediated radical polymerization

Abstract: SUMMARY: TEMPO-mediated free radical polymerization was employed for homo-and copolymerization of vinylferrocene (Vfc). Homopolymerization of Vfc resulted in relatively narrow polydispersities (M

Cited by 32 publications

References 23 publications

Organometallic Polymers of the Transition Metals

Organometallic Polymers of the Transition Metals

Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units

Progress on the synthesis and catalytic and anti‐migration properties of ferrocene‐based burning rate catalysts

Contact Info

Product

Resources

About