Abstract:The influences of ZnEt2 on ethylene chain transfer polymerization were investigated in detail and the polymerization mechanism was thoroughly analyzed. The results indicated that ZnEt2 contributed greatly to increase the activity of α-diimine nickel complex/ZnEt2/MAO(MAO: methylaluminoxane). It was striking that α-diimine nickel complex/ZnEt2 catalyst system (1/100 mol/mol) exhibited 8.0 ×104g/mol∙h activity, it was possible the formation of the ion pairs of Nickel and Zinc was convenient for ethylene chain pr… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.