To enhance the luminous intensity of phosphors containing Tb 3 + , Gd 3 + was used as a sensitizing ion to recombine with Tb 3 + . Gd 3 + and Tb 3 + ions were loaded on the Al 2 O 3 aerogel matrix with nano porous structure via a simple and facile solgel method. After vacuum drying and calcination, Al 2 O 3 : Tb 3 + , Gd 3 + composite aerogel materials were obtained. Al 2 O 3 aerogel matrix has three-dimensional nanostructure and good chemical stability, which can provide stable crystal field and emission site for the rare earth activated ions. The results indicated that the introduction of Gd 3 + can effectively enhance the luminescence intensity of Al 2 O 3 : Tb 3 + at 543 nm under 260 nm UV excitation. The optimal ratio of Gd 3 + and Tb 3 + was determined to be 1: 1. The mechanism of Gd 3 + sensitization to Tb 3 + can be considered as electric multipole resonance transmission. We expected that this work could provide guidance for the development of enhancing the luminous intensity of green phosphors for lamp.