The combustion characteristics of ammonia−natural gas (NH 3 − NG) blends are usually studied using ammonia−methane (NH 3 −CH 4 ) blends. However, the ignition characteristics of NH 3 −NG and NH 3 −CH 4 are different due to ethane (C 2 H 6 ) and propane (C 3 H 8 ) in NH 3 −NG. In the present study, a natural gas fuel model (96.73% CH 4 , 2.59% C 2 H 6 , and 0.68% C 3 H 8 in molar fraction) was constructed using the real composition of China natural gas to investigate the ignition delay times (IDTs) of NH 3 −NG. The IDTs of pure NH 3 , 50% NH 3 −50% CH 4 , 50% NH 3 −50% NG, and pure NG were measured experimentally using a high-pressure shock tube under an ignition pressure (P i ) of 10 bar, ignition temperatures (T i ) ranging from 1450 to 1900 K, and with 95% argon (Ar) dilution. The NUIG mechanism was selected for investigating chemical reaction kinetics. The IDTs for the fuels follow this order: 100% NH 3 > 50% NH 3 −50% CH 4 > 50% NH 3 −50% NG > 100% NG. At T i = 1600 and 1800 K, the IDTs for NH 3 −NG are 38.4 and 33.3% shorter than NH 3 −CH 4 , respectively. Adding C 2 H 6 and C 3 H 8 increases the CH 3 radical mole fraction during the first half of the ignition process (0−0.5 IDTs). During this stage, C 2 H 6 participates in the NH 2 → NH 3 transition via reaction C 2 H 6 + NH 2 ⇔ C 2 H 5 + NH 3 (R11); in the meantime, the C 3 H 8 is depleted through the reaction C 3 H 8 (+M) ⇔ C 2 H 5 + CH 3 (+M) (R9). During the second half of the ignition process (0.5−1.0 IDTs), the differences between NH 3 −CH 4 and NH 3 −NG become insignificant. C 2 H 6 and C 3 H 8 mainly affect the first half of the NH 3 −NG ignition process, resulting in shortened IDTs.