Study on the Microstructure Evolution and Strength Damage Mechanism of Dolomite under Dissolution Condition

Abstract

Dolomite is a common type of natural soluble rock. The strength of rock decreases under the action of corrosion, which has a significant impact on the self-stability and long-term safety of the tunnel surrounding the rock. To reveal the microscopic structure evolution and strength-damage law of carbonate rock caused by chemical corrosion, a series of tests such as rock chemical corrosion test, rock uniaxial compression test and electron microscope scanning test are conducted at different pH values on the dolomite of the Doushantuo Formation. The rock dissolution at different pH values exhibits four typical stages: the initial dissolution stage, secondary dissolution acceleration stage, stable dissolution rate stage and dissolution attenuation stage. During the dissolution process, the initial dissolution rate is 25.91 times that of the stable stage, and the maximum strength attenuation is 76.2% after 21 days of dissolution. For macroscopic failure, the rock is developed from 1 to 2 external fractures to multiple internal and external fractures and penetrated, and the specimen transforms from brittle to flexible. For microstructure, the sample exhibits corrosion characteristics along the joint surface, intensified corrosion at the edge, etc. The porosity increase rate is 0.6%/d; however, the length–width ratio of the pores is maintained at 1.7–1.85, indicating that the development rate of pores in different directions is similar. The results of this study have enriched the study of the dolomite dissolution mechanism and, in addition, have important reference value for the stability evaluation of tunnel surrounding rock in karst environments.

Advances in the Experiments of Leaching in Cement-Based Materials and Dissolution in Rocks

“…Due to the fact that rocks are composed of particles of different sizes, dissolution is relatively strong in intergranular and intergranular pores, as well as in various types of fractures [100]. The dissolution of dolomite can be divided into four stages: the initial dissolution stage, secondary dissolution acceleration stage, stable dissolution rate stage, and dissolution attenuation stage; the dissolution rate of initial stage is much greater than the stable stage [101]. In addition, acidic solutions rich in hydrogen ions such as acid rain can also cause corrosion when in contact with carbonates [102,103].…”