Thermal conductivity κ(T)
and thermoelectric power S(T)
studies on (Y,Gd)Ba2(Cu1−xMnx)3O7−δ
(x≤0.02) superconductors are presented here. Thermal conductivity for all the
samples exhibits a hump below the superconducting transition temperature
Tc. The
peak height of the hump decreases with the Mn content in both the Y- and Gd-based systems, barring
GdBa2(Cu0.99Mn0.01)3O7−δ. The peak height reduction in the Gd-based cuprates is much faster
(∼one fourth) compared to the Y-based samples. The thermoelectric power (TEP) of the Y-based samples for
x≤0.0075 is electron-like (up to
∼140 K) whereas it turns
to hole-like even at x = 0.005
for the Gd-based system. On the basis of the structure of the thermal conductivity hump, and of the
electron- or hole-like nature of the thermopower, it has been argued that, in the Y-based system up
to x = 0.0075, Mn produces qualitatively the same effect as Gd in the Gd-based system. An analysis
of the thermal conductivity data in terms of lattice theory, and the TEP data
in terms of a narrow-band picture, has been made to invoke the role of Mn in
these systems. Boundary scattering, point defects and sheet-like faults (from
κ(T) data analysis) and
chemical potential (from S(T)
data analysis) support different roles of Mn for
x≤0.0075
and x>0.0075.