2016
DOI: 10.3390/min6040106
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Study on Selective Removal of Impurity Iron from Leached Copper-Bearing Solution Using a Chelating Resin

Abstract: Abstract:In order to selectively remove iron from copper laden solution after leaching but prior to electrowinning, equilibrium, kinetic, and thermodynamic studies have been conducted on an a chelating resin of Rexp-501 at pH 1.0 and at various temperatures. Both Langmuir and Freundlich models were investigated, with the Langmuir model proving to be more suitable for fitting iron removal performance, with little influence from copper concentration. Compared with the pseudo first order kinetic model, the pseudo… Show more

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Cited by 10 publications
(2 citation statements)
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References 36 publications
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“…These parameters and correlation coefficients ( R 2 ) were listed in Table . The correlation coefficients of pseudo‐second‐order kinetics were obviously better than those of pseudo‐first‐order kinetics, indicating that the adsorption reactions followed pseudo‐second‐order kinetics, and suggesting that the adsorption may be chemisorption (Ho & Mckay, ; Li, Wang, Xiao, & Zhang, ; Li, Liang, et al., ; Liao, Ding, Wang, & Shi, ). For phosphorus uptake, the calculated adsorption capacities of OP and IP were 12.48 mg/g and 15.98 mg/g, respectively, which were in good agreements with the measured data.…”
Section: Resultsmentioning
confidence: 99%
“…These parameters and correlation coefficients ( R 2 ) were listed in Table . The correlation coefficients of pseudo‐second‐order kinetics were obviously better than those of pseudo‐first‐order kinetics, indicating that the adsorption reactions followed pseudo‐second‐order kinetics, and suggesting that the adsorption may be chemisorption (Ho & Mckay, ; Li, Wang, Xiao, & Zhang, ; Li, Liang, et al., ; Liao, Ding, Wang, & Shi, ). For phosphorus uptake, the calculated adsorption capacities of OP and IP were 12.48 mg/g and 15.98 mg/g, respectively, which were in good agreements with the measured data.…”
Section: Resultsmentioning
confidence: 99%
“…From literatures, the adsorption isotherm of mixed metal ion solution have been reported. For example, the adsorption isotherm of mixed metal ions solutions (Ag(I), Cu(II), Fe(II), and Pb(II)) by an aminated polyacrylonitrile nanofiber mat using ICP technique was fitted with the Langmuir adsorption isotherm 42 . Therefore, the high sample throughput analytical process by using AAS or ICP is necessary for the selective adsorption of mixed metal ions study.…”
Section: Effect Of Contact Time Ph and Initial Concentration On Cu(ii) Adsorptionmentioning
confidence: 99%