“…Recently, the nonlinear optical materials with enhanced third order nonlinear optical susceptibility χ 3 have been used in wide range of applications such as 3D optical memory, optical switching, optical modulating, laser technology, optical communication, optical storage technology and optical limiting etc,. In the few decades, many organic and inorganic materials have been developed to cover the possible applications in Ultraviolet (UV), near and far-infrared (IR) wavelength regions [1, 2, 3, 4, 5, 6, 7, 8]. Inorganic crystals have high laser-induced damage threshold energy compared to organic crystals, the materials with high nonlinear absorption, ultra fast response time and large third order optical nonlinearity are essential in two photon laser scanning microscopy, phase conjugation, low intensity lasers and microfabrication [9].…”